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h8$B*OJQJUaJph'h h8$B*H*OJQJaJo(ph$h h8$B*OJQJaJo(ph2 MnO22H2O + O2!bvQNTtT{Hh 5 NaNO2 (6)(3a  4b)KJ/mol 0㉐g0,gge:girv'`( mSSf[(u0e z_fNQ0'lS؏SS^NSpSf[vwƋ0N~Qvh ~TT(WhTghvMOnNepevI{ُNagN N_QT:NAl Q:NC R:NN W:NS01 T:NAl 13SCQ }02 S0CgؚN'lSir[^vx:Nkxx:_Nxx RS_^ё^\'`S:_NC03 SNH2SO4SuR_-NS^ NCQ }[R` w [ g4lub SY:NNlSO NSTN w S/fSO204 kR(P[peY1vCQ }:NO X[(WH2O2lS:NH2OvS^05 N-Nv[RP[(ϑg\v'lSir:NNO 2NO + O2 = 2NO2 >f6qNOǏϑ1L Teub1LvNO2 Q(uNaOH8T6e N'lS؏S҉^ w +2NNvNON+4NNvNO2 ^R_-Nub+3NvSTirNaNO206 C + O2  EMBED Equation.3 CO2 DH= a Kj/mol = 1 \* GB3 `$ 4Al +3 O2 =2Al2O3 DH= 4bKj/mol = 2 \* GB3 a$0AlNCO2vnbcS^ QQS^e z_:N4Al + 3CO2 EMBED Equation.3 3C + 2Al2O3 dkS^vDH:NS1u = 2 \* GB3 a$  = 1 \* GB3 `$3_ DH= 4b (-3a)=(3a-4b)Kj/mol. w.w.w.k.s.5.u.c.o.m 24.13R NݔWw;NbR/f EMBED Equation.DSMT4  +T EMBED Equation.DSMT4 0 EMBED Equation.DSMT4 0MgOI{Bg( -NcS$Ny]zTvAm zY N  VT{ NR 1 Am z2uReQvxTubAl3+ve z_:N_________. 2 Am zYNReQpxTubSi EMBED Equation.DSMT4 vyP[e z_:N________. 3 nmB+T EMBED Equation.DSMT4  SS\ϑnmv^ReQ________kXՋBR Ty 0 4 nmE0K-Nn(v;NbN/f________(kXSf[_) QQ勶nmvNy(u________ 5 ]w298Ke  EMBED Equation.DSMT4 v[^y8^pe EMBED Equation.DSMT4 =5.6 EMBED Equation.DSMT4 ,SϑvnmB,ReQN[ϑvpx0Rlmnms^a Km_PH=13.00 Rdk)n^ NkYu(Wnm-Nv EMBED Equation.DSMT4 =_______. T{Hh1 Al2O3 + 6H  EMBED Equation.3 2Al3 +3H2O (2)SiO2 + 2OH  EMBED Equation.3 SiO32 + H2O (3)kx0lSbkx0lx0ZnmI{TtT{Hh 4 NaHCO36R~xbZPSu|I{TtT{Hh 5 5.610-10mol/L 0㉐g0,ggݔWw-N'lSݔcSv]zAm z01 NHClS^ubAl3 ^:NݔWw-NAl2O302 SiO2SNnNNaOH-NubNa2SiO303 hFe3 vyr_S^_Y YNKSCN>f@~r NZ>f+}r NOH >f~rlmI{04 ubE0Ke CO2GW/fǏϑv Ee^ubNaHCO305  EMBED Equation.3   EMBED Equation.3 =5.610-12/(0.1)2=5.610-100 25.(17R) gxvz'`\~PRA-DvNhVňn[b gsQ[  0[N06eƖNOlSO0 (uňnA6eƖNOlSO cknxvd\O N kX^S 0 a.N`$Sۏl (uc4llƖl b.N`$Sۏl (ucllƖl c.Na$Sۏl (uc4llƖl d..Na$Sۏl (ucllƖl 0[N0:NNcvz@ g Nv v(ϑRpe EMBED Equation.DSMT4 T@B\S^ g⋗_w fnNxZn+2NaOH=Na2ZnO3+H2!ncdk *bSby:NSvSb@ gՋ7h jRx0y_(ϑ:Nm1 g0(uVSOpxT4l\OՋBR bQ NR[eHhv^ۏLvsQ[0 eHh2uǏKmϑՋ7hNxS^ubv"llSOyeg[scvz(gvh0 2 (uBT kXNhVhS $N*NňnۏL[0 3 Km_EQRS^Tub"llvSOy:NVLhQrQ  EMBED Equation.DSMT4 = 0 4 {@B\S^ ؏h"}vN*Nirtϑ/f 0 5 ňnB-NvR`SRmoe9e:NnfRmoe Kmϑ~g\kX OP'Y 0 OP\ b eq_T 0 eHhYNǏyϑՋ7hNxS^MRTv(ϑ[scvzvh0 (uNhVCZP[ Ջ7h~EQRS^ nQ Nnir0mm0pr^ y_vQ(ϑ:Nm2g 0 6  EMBED Equation.DSMT4  0 eHhNǏyϑՋ7hNxS^MRTNhV0Ջ7hTՋBRv;`(ϑvQ]f6q]'Y V:NNuvH2(ϑ_\ {OP]'Y0 2625R VT{ NR`!0a! `!.SVh:yv/fKm[OnvhQ)n^SS[ňn0gxvz\~Nňncvzuk̃(W N TagN N|T8T\O(uv`Q0Pge(uwQO)nvh500mL 0)n^;m'`r^uk0(ϑSm^0.1g/mLva|nm0h0w!l0 [GPuk̃(W g'lagN N|T8T\O(uke'lagN N|T8T\O(u>eQpϑfY0 1 SA0B$Nňn[Y N eEQ Nh-NQ[ ňnelekNelekNelek NAReQ240mlva|nmReQ10g;m'`r^uk`$ BReQ240mlnqlTQtSva|nma$ ReQw!l nmb  2 Bňna|nmnqlv;Nvv/f ُ/fc6R[v Sϑ0 3 Km[BňnV|T8T\O(u_wv)n^SSϑ ؏XRN*NňnC0QQňnCv[ek ňnelekNelekNelek NCb$ c$ ReQw!l nmb 4 [g(W[agN N[ 30RTU_[~g ňnA0B0C)n^'Y\sQ|/f  (u <0=0> h:y RGPbz0 a!.NSOSO)nYOcv[R`[ /f1uNNpϑTcepϑOcR`s^av~g0VT{ 1 S_SOvQɉaShVS0R[Q:Roe NuvtQKY1u O NNSO)n-Ng S_w  RlXY o }\O(uNhQ~ހ cؚ~ހN"v^ XRNpϑ(W38!vؚ)nsX-N NSO;NǏ e_cep0 2 S_SOQ gpueOQsSpsa ُ g)RNTlV~ހTb̃ir(I{lypu:S b_uSSOv;eQ dkǏ z^\N MQu0NSOl\YNWAmauׂT ǏSOmMQuT~ހMQu Nuvv^  NƋ+Rv^\O(uNOeQ:gSOv2uWH1N1Amauk0 T{Hh`!.1 `$ NReQw!l a$ReQ10g;m'`r^uk 2 Sd'll 3 b$ReQ240mLnqlTQtSva|nm c$ NReQ;m'`r^uk 4 A>B>C a!(1) OeQ^y~ 2urzo }b Nz } WlmS 2 ^yr_'` bSO*NHe^T~ހ 0㉐g0`!.,ggǏcvzuk̃(W g'lagN NTe'lagN N|T8T\O(u>eQpϑv`Q0Rgh-NvsQQ[ Q0R[u_[gq'`SR0yf['`SRTUSNSϑSRُQ*NSR Vdk`$Y^kX NReQw!l a$Y^kXReQ10g;m'`r^uk0Bňna|nmnqlv;Nvv/fSd'll ُ7hegc6R[vSϑ0Km[BňnV|T8T\O(u_wv)n^SSϑ ؏XRN*NňnC Vdk^bzz}v[gq sSb$ReQ240mLnqlTQtSva|nm c$ NReQ;m'`r^uk0V:N g'lagN Nke'lagN N|T8T\O(u>eQpϑY Vdk ňnA0B0C)n^'Y\sQ|/fA>B>C0 a!.,ggNSOSO)nvvsQQ[0N*N[tevS\'_^1uaShV0 OeQ^y~0^y~-Ng0 OQ^y~THe^hVN*NRgb0S_SOvQɉaShVS0R[Q:Roe NuvtQKY^Ǐ OeQ^y~ O NNSO)n-Ng S_w2urzo }b No } RlXY V:Nُ$No }Ycؚ~ހN"v^ Oۏir(v'lSR XRNpϑNSOcepv;NhV[/fv (W38!vؚ)nsX-N NSO;NǏWlmSe_cep0S_SOQ gpueOQsSpsa TlV~ހTb̃ir(I{lypu:S b_uSSOv;eQ Ǐ z NwQ gyr_'` @bN/f^yr_'`MQu0NSOl\YNWAmauׂT ǏSOmMQuNuvv^bSO T~ހMQuNuHe^T~ހ NƋ+Rv^\O(uNOeQ:gSOv2uWH1N1Amauk SƋ+Rv^\O(uNOeQ:gSOvYNWAmauk0  2715R  gygrISOQb_b0lv_:NMRSOir(!N0l|!0l 0WVAc6RMRSOir(ubN0l| WVBc6RN0l|ub0l0hsWNWVWKNv[^sQ|Y Nh hsW g0l gN0l|0e0leN0l0e0lWVWA_B_ATB TeX[(W A_bbAX[(W B NX[(W aaB_baabbA NX[(W  1 (W g0lgrIAABB TN-NQsvzS*NSOAAbb V:ONv^vv hse0l'`r YgWVbNBvlU_NirKNS gN*N[xP[vxW^R N T RыmRNAv勹peSuvSSS/fxv(lWx b/f 0 2 N0lb_b gsQvN[WV1u~T0$N*Ne0lvN,gBgN F1GWhs:N0l RF1NWVW:Naabbv*NSOBgN P[NvhsWSkO:N 0 3 ؚNwR+R1uWVE0ec6R0N,g2uAABBEE TN,gYNaabbee BgN F1GWhs:N0l0ؚ0GP N[I{MOWV1u~T RF2-N3z[W Ove0l0ؚ*NSO`S 0 4 N g0l0ؚNe0l0w$N*N3z[W OvgrI:NN,g ǏBgNy Sel_ee0l_NeN0l|vؚgrI0NW OV㉀{f0 T{Hh1 y{| N T Tb~bkbы~bk 2 g0l0e0l=103(b g0l0 gN0l|0e0l0eN0l|0e0l=10102)0 3 3/64 4 AABBEEAAbbee  AABbEe  EMBED Equation.DSMT4  TN-Nl g&{TBlvaaB_E_baabbE_v*NSO 0㉐g0,ggWV['`rvc6Rv gsQwƋ0t$YgWVbNBvlU_NirKNS gN*N[xP[vxW^R N T RыmRNAvMOpeSuvSSS/fxv(lWxy{| N TINzS b/fTb~bkbы~bk eINzS 勁zS NS/f TINzS 0 u$Oa SN:NAAbbTaaBB F1:NAaBb AaBbNaabbBgN_1AaBb 1aaBb 1Aabb 1aabb P[NvhsWSkO:N g0l0e0l=103(b g0l0 gN0l|0e0l0eN0l|0e0l=10102)0 v$N,g2uAABBEE TN,gYNaabbee BgN F1 :NAaBbEe RF2-N3z[W Ove0l0ؚ*NSO:NAAbbEE 0aaBBEE0aabbEE `S1/41/41/4+1/41/41/4+1/41/41/4=3/640 w$ N g0l0ؚAABBEE Ne0l0wAAbbee $N*N3z[W OvgrI:NN,gBgN W OV㉂Y N AABBEEAAbbee  AABbEe  EMBED Equation.DSMT4  TN-Nl g&{TBlvaaB_E_baabbE_v*NSO Vdkel_ee0l_NeN0l|vؚgrI0  R ,{IIwS RqQ5 qQ35R0vQ-N,{28029:Nirt ,{30031:NSf[ uN$NSirt0$NSSf[-NTN N\OT{ ,{28029\OT{ R c,{28R ,{30031\OT{ R c,{30R ,{32:Nuir /f_T{0\T{HhkXQ(WT{aS T{:SWvc[MOn N0 28.[irt  O3-3],gqQ g$N\ k\6R qQ12R0k\S gN*N y&{Ta0 1 sNyf[b/gvSU\NPgeyf[0nv_S[RvsQ NRsQNPge0nvlcknxv/f 0kX yMRvS `$Swn:Nnmn a$~s|Pgev|^(W1-100mKN b$JS[SOPgev[5u'`NNё^\[SOT~SOKN c$mvfe gmSOvAmR'` S gIQf['`(vTT T'` 2 N[(ϑvt`lSO(WgNǏ z-N YLu[lSOZPR7.0104J,lSOQQ\1.3105J RdkǏ z 0kX yMRvS `$lSONYLu8T6epϑ2.0105J a$lSOTYLu>eQpϑ2.0105J b$lSONYLu8T6epϑ2.0104J c$lSOTYLu>eQpϑ6.0104J T{Hh1  = 3 \* GB3 b$2  = 2 \* GB3 a$ 0㉐g01 SwnqpeNuN'lSx b)n[lSOHe^dqxTwl-N+T gkx qpeNuN'lSkxI{ir(O4lvx^XؚI{I{ fSwn N/fnmn = 1 \* GB3 `$ ~s|Pgev|^(W1-100nm N/f1-100m  = 2 \* GB3 a$ mvfe gmSOvAmR'` S gIQf['`(vTT_'` N/f T'`  = 4 \* GB3 c$0 cknx y:N = 3 \* GB3 b$ 2 W=7.0104J U=-1.3105J 1upRf[,{N[_ W+Q=U Q=-2.0105J hflSOTYLu>ep2.0105J cknx y:N = 2 \* GB3 a$ 29.[irt  O3-5],gqQ g$N*N\ k\6R qQ12R0k\S gN*N y&{Ta0 1 @wsNyf[vSU\ 'Yϑvyf[SU\OۏNNN[SP[0SP[8hvƋ NR gsQSP[0SP[8hvScknxv/f 0kX yMRvS `$bS_ty|P[ce\[fSP[8hQwQ g YBgv~g a$)Y6q>e\sahfSP[8hQ g5uP[ b${8hSS^e z g EMBED Equation.DSMT4  c$"lSP[Nn=3~Í0Rn=1~TNn=2~Í0Rn=1~ MRÍ\QvIQP[lkTv 2 NpG;`(ϑ:NM N^ EMBED Equation.DSMT4 SLv N9 NNv[wm\v4ls^^ EMBED Equation.DSMT4 lMRۏeT\QN(ϑ:Nmvp9_ S\p9_TGv^:N EMBED Equation.DSMT4  N4lv;R R NRTsQ|_-Ncknxv/f 0kX yMRvS `$ EMBED Equation.DSMT4  a$  EMBED Equation.DSMT4  b$ EMBED Equation.DSMT4  c$ EMBED Equation.DSMT4  T{Hh1  = 3 \* GB3 b$2 `$ 0㉐g01 bS_tyǏ|P[ce\[cQSP[8h_~g!jW )Y6q>e\safSP[8hQwQ g YBgv~g = 1 \* GB3 `$ )Y6q>e\~-N>eQv|P[/fSP[8h-NvN*N-NP[pS:N(P[>eQv5uP[ SP[8hQv^l g5uP[0 = 2 \* GB3 a$ "lSP[Nn=3~Í0Rn=1~>eQvIQP[ϑkNn=2~Í0Rn=1~'Y 1ulQ_ EMBED Equation.3 Sw MRÍ\QvIQP[lkTvw c$0 cknx y:N = 3 \* GB3 b$ 2 Rϑ[R`[__{v[N TϑS|0,g-NvT*N^/fv[N0Wbv Nlbc0S\p9_MR|~v;`Rϑ:NMv0S\p9_T p9_vRϑ:Nmv0,9vRϑ:NM-m v2 @bNRϑ[R`[_vh_:N  EMBED Equation.DSMT4  cknx y:N`$ 30.[Sf[  ir(~gN'`(]13R Q0R0X0Y0ZNyCQ }vSP[^peO!kX0]w `$ZvSP[^pe:N29 vQYOvGW:NwhTg;NeCQ } a$YSP[N5uP[YV5uP[ c^msnmpn b$RSP[8hYLB\5uP[pe:NGYpe c$Q0XSP[phSv5uP[peR+R:N2T40 VT{ NR 1 Z2+ v8hY5uP[c^_/f 0 2 (W[Z(NH3)4]2+yP[-N Z2+vzzhSSNH3RP[cOv b_bMMO.0 3 QNYb_bvg{USl`"lSirR+R:N2u0YN NR$Recknxv/f 0 a.3z['`2u>YN lp2u>YN b.3z['`2u>YN lp2u>YN c.3z['`2u<YN lp2u<YN d.3z['`2u<YN lp2u>YN (4) Q0R0Y NyCQ }v,{N5uypeSiH40V:NSiH4 vv[RP[(ϑkCH4'Y EeRP[\O(uR'Y lpؚ04 C0NTSi-N C0SiMON TN;Ne R Nbv^ё^\'`:_ Ee,{N5uy'Y N1uNwQ gJSEQnr` Ee,{N5uykvCQ }'Y @bNN>C>Si05 C0Hb_bvv[RP[(ϑvir(:NC2H2 ~g_:NH-Ca"C-H US./f. 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